显示标签为“316L”的博文。显示所有博文
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2016年6月27日星期一

[ Wiki ] DIFFERENCE BETWEEN ANNEALING AND TEMPERING




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Heat Treatments


Heat treatments are used to alter the physical and mechanical properties of metal without changing its shape. They are essential processes in metal manufacturing which increase desirable characteristic of metal, while allowing for further processing to take place.
Various heat treatment processes involve carefully controlled heating and cooling of metal. Steel, for example, is commonly heat treated for use in a variety of commercial applications.
Common objectives of heat treatment are to:
  • Increase strength
  • Increase hardness
  • Improve toughness
  • Improve machining
  • Improve formability
  • Increase ductility
  • Improve elasticity
How Heat Affects Metal
The cooling stage has different effects depending on the metal and process. When steel is cooled quickly it hardens, whereas the rapid cooling stage of solution annealing will soften aluminum.
While there are many types of heat treatment, two important types are annealing and tempering.

Annealing


Annealing involves heating steel to a specified temperature and then cooling at a very slow and controlled rate.
Annealing is commonly used to:
  • Soften a metal for cold working
  • Improve machinability
  • Enhance electrical conductivity
Annealing also restores ductility. During cold working, the metal can become hardened to the extent that any more work will result in cracking. By annealing the metal beforehand, cold working can take place without any risk of cracking, as annealing releases mechanical stresses produced during machining or grinding.
Annealing is used for steel, however, other metals including copper, aluminum and brass can be subject to a process called solution annealed.
Large ovens are used for annealing steel. The inside of the oven must be large enough to allow air to circulate around the metal. For large pieces, gas fired conveyor furnaces are used while car-bottom furnaces are more practical for smaller pieces of metal.
During the annealing process, the metal is heated to a specific temperature where recrystallization can occur. At this stage, any defects caused by deformation of the metal are repaired. The metal is held at that temperature for a fixed period, then cooled down to room temperature.
The cooling process must be done very slowly to produce a refined microstructure, thus maximizing softness. This is often done by immersing the hot steel in sand, ashes or other substances with low heat conductivity, or by switching off the oven and allowing the steel to cool with the furnace.

Tempering


Tempering is used to increase the toughness of iron alloys, particularly steel. Untempered steel is very hard but is too brittle for most applications. Tempering is commonly done after hardening to reduce excess hardness.
Tempering is used to alter:
  • Hardness
  • Ductility
  • Toughness
  • Strength
  • Structural stability
Tempering involves heating the metal to a precise temperature below the critical point, and is often done in air, vacuum or inert atmospheres.
The temperature is adjusted depending on the amount of hardness that needs to be reduced. While it varies depending on the metal type, generally, low temperatures will reduce brittleness while maintaining most of the hardness, while higher temperatures reduce hardness which increases elasticity and plasticity, but causes some yield and tensile strength to be lost.
It is essential to heat the metal gradually to avoid the steel being cracked. The metal is then held at this temperature for a fixed period. A rough guideline is one hour per inch of thickness. During this time the internal stresses in the metal are relieved. The metal is then cooled in still air.

2016年5月24日星期二

[ Wiki ]Stainless Steel - Grade 316L - Properties, Fabrication and Applications (UNS S31603)



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Chemical Formula

Fe, <0.03% C, 16-18.5% Cr, 10-14% Ni, 2-3% Mo, <2% Mn, <1% Si, <0.045% P, <0.03% S

Background

Grade 316 is the standard molybdenum-bearing grade, second in importance to 304 amongst the austenitic stainless steels. The molybdenum gives 316 better overall corrosion resistant properties than Grade 304, particularly higher resistance to pitting and crevice corrosion in chloride environments.
Grade 316L, the low carbon version of 316 and is immune from sensitisation (grain boundary carbide precipitation). Thus it is extensively used in heavy gauge welded components (over about 6mm). There is commonly no appreciable price difference between 316 and 316L stainless steel.
The austenitic structure also gives these grades excellent toughness, even down to cryogenic temperatures.
Compared to chromium-nickel austenitic stainless steels, 316L stainless steel offers higher creep, stress to rupture and tensile strength at elevated temperatures.

Key Properties

These properties are specified for flat rolled product (plate, sheet and coil) in ASTM A240/A240M. Similar but not necessarily identical properties are specified for other products such as pipe and bar in their respective specifications.

Composition

Table 1. Composition ranges for 316L stainless steels.
Grade

C
Mn
Si
P
S
Cr
Mo
Ni
N
316L
Min
-
-
-
-
-
16.0
2.00
10.0
-
Max
0.03
2.0
0.75
0.045
0.03
18.0
3.00
14.0
0.10

Mechanical Properties

Table 2. Mechanical properties of 316L stainless steels.
Grade
Tensile Str
(MPa) min
Yield Str
0.2% Proof
(MPa) min
Elong
(% in 50mm) min
Hardness
Rockwell B (HR B) max
Brinell (HB) max
316L
485
170
40
95
217

Physical Properties

Table 3. Typical physical properties for 316 grade stainless steels.
Grade
Density
(kg/m3)
Elastic Modulus
(GPa)
Mean Co-eff of Thermal Expansion (µm/m/°C)
Thermal Conductivity
(W/m.K)
Specific Heat 0-100°C
(J/kg.K)
Elec Resistivity
(nΩ.m)
0-100°C
0-315°C
0-538°C
At 100°C
At 500°C
316/L/H
8000
193
15.9
16.2
17.5
16.3
21.5
500
740

Grade Specification Comparison

Table 4. Grade specifications for 316L stainless steels.
Grade
UNS
No
Old British
Euronorm
Swedish
SS
Japanese
JIS
BS
En
No
Name
316L
S31603
316S11
-
1.4404
X2CrNiMo17-12-2
2348
SUS 316L
Note: These comparisons are approximate only. The list is intended as a comparison of functionally similar materials not as a schedule of contractual equivalents. If exact equivalents are needed original specifications must be consulted.

Possible Alternative Grades

Table 5. Possible alternative grades to 316 stainless steel.
Grade
Why it might be chosen instead of 316?
317L
Higher resistance to chlorides than 316L, but with similar resistance to stress corrosion cracking.

Corrosion Resistance

Excellent in a range of atmospheric environments and many corrosive media - generally more resistant than 304. Subject to pitting and crevice corrosion in warm chloride environments, and to stress corrosion cracking above about 60°C. Considered resistant to potable water with up to about 1000mg/L chlorides at ambient temperatures, reducing to about 500mg/L at 60°C.
316 is usually regarded as the standard “marine grade stainless steel”, but it is not resistant to warm sea water. In many marine environments 316 does exhibit surface corrosion, usually visible as brown staining. This is particularly associated with crevices and rough surface finish.

Heat Resistance

Good oxidation resistance in intermittent service to 870°C and in continuous service to 925°C. Continuous use of 316 in the 425-860°C range is not recommended if subsequent aqueous corrosion resistance is important. Grade 316L is more resistant to carbide precipitation and can be used in the above temperature range. Grade 316H has higher strength at elevated temperatures and is sometimes used for structural and pressure-containing applications at temperatures above about 500°C.

Heat Treatment

Solution Treatment (Annealing) - Heat to 1010-1120°C and cool rapidly. These grades cannot be hardened by thermal treatment.

Welding

Excellent weldability by all standard fusion and resistance methods, both with and without filler metals. Heavy welded sections in Grade 316 require post-weld annealing for maximum corrosion resistance. This is not required for 316L.
316L stainless steel is not generally weldable using oxyacetylene welding methods.

Machining

316L stainless steel tends to work harden if machined too quickly. For this reason low speeds and constant feed rates are recommended.
316L stainless steel is also easier to machine compared to 316 stainless steel due its lower carbon content.

Hot and Cold Working

316L stainless steel can be hot worked using most common hot working techniques. Optimal hot working temperatures should be in the range 1150-1260°C, and certainly should not be less than 930°C. Post work annealing should be carried out to induce maximum corrosion resistance.
Most common cold working operations such as shearing, drawing and stamping can be performed on 316L stainless steel. Post work annealing should be carried out to remove internal stresses.

Hardening and Work Hardening

316L stainless steel does not harden in response to heat treatments. It can be hardened by cold working, which can also result in increased strength.

Applications

Typical applications include:
         Food preparation equipment particularly in chloride environments.
         Pharmaceuticals
         Marine applications
         Architectural applications
         Medical implants, including pins, screws and orthopaedic implants like total hip and knee replacements
         Fasteners